Characterizing Structure, Properties, and Deformation in Metallic Glasses and Olivine Using Instrumented Nanoindentation
Date of Award
Doctor of Philosophy (PhD)
Micro- and nanomechanical testing can provide significant insight about the structure, properties, and behavior of materials. These techniques are nondestructive, require only limited amounts of material, and have been known to detect a brittle-to-ductile transition in mechanical behavior due to a size effect. This work utilizes this type of testing to explore fundamental questions about the structure, properties, and behavior of two disparate material systems: metallic glasses and olivine.
Metallic glasses are metallic alloys devoid of any long-range order. Their unique atomic structure imbues them with properties such as a high elastic strain limit, near-theoretical strengths, and the ability to be thermoplastically formed. Despite their high strengths, metallic glasses suffer from an intrinsic lack of tensile ductility compared to other high-performance materials. Recent studies have shown that the macroscopic deformation behavior of these materials might be controlled by structural heterogeneities, the exact nature of which remains ill-defined. To further this area of research, the heterogeneous microstructure of a Zr-based monolithic bulk metallic glass as well as the glass phase of a Ti-based bulk metallic glass matrix-crystalline composite was investigated using nanoindentation and dynamic modulus mapping. Significant spatial variations in the mechanical properties measured by both techniques suggest a hierarchical arrangement of mechanical heterogeneities in bulk metallic glasses and their composites. Moreover, a previously unobserved elastic microstructure, comprising an interconnected network of elastic features, was revealed by dynamic modulus mapping. Parameters such as aspect ratio and orientation of the microstructural features were defined here, which highlighted the presence of microstructural domains or colonies in the elastic microstructure. The effects of heat treatment and deformation on these heterogeneities were also investigated.
The rheology of olivine plays an important role in the dynamics of Earth__s upper mantle. At conditions of low temperature and high stress, such as in semi-brittle regions of the lithosphere, the deformation mechanism transitions into low temperature plasticity. Low temperature plasticity is difficult to study in typical laboratory conditions, requiring high confining pressures to suppress cracking in favor of dislocation glide. Low temperature plasticity of olivine was investigated using nanoindentation and micropillar compression. Nanoindentation provided a means of achieving plastic deformation in the absence of cracking, but measurements obtained via this method are notoriously difficult to translate into uniaxial properties. Using available models to obtain these properties, the data were fit to an established low temperature plasticity flow law, which predicted Peierls stresses for the olivine in the range of 5.32 __ 6.45 GPa. As a complement to the nanoindentation, room temperature plasticity was also achieved using micropillar compression. While some of the pillars exhibited catastrophic shearing after a dwell time during creep testing, other pillars showed evidence of plastic deformation after creep testing that was confirmed to be dislocation slip. The data obtained from the micropillar compression was in good agreement with the flow law fits from the nanoindentation. These results provide increased confidence in the extrapolation of high-pressure and high-temperature laboratory experiments to low-temperature conditions and illustrate the applicability of micromechanical testing methods to the study of mineral rheology.
Katharine M. Flores
Kenneth Kelton, Shankar Sastry, Philip Skemer, Simon Tang,
Permanent URL: https://doi.org/10.7936/K70K270R