Date of Award
Doctor of Philosophy (PhD)
Dynamic nuclear polarization nuclear magnetic resonance (DNP NMR) exploits internal electron spin and nuclear spin interactions to increase sensitivity and uncover valuable information regarding structure and dynamics of a system. To manipulate these interactions, instrumentation is developed to combine high-power microwave and radiofrequency irradiation with the ability to spin samples at the magic angle (MAS) at temperatures from 90 K to 4.2 K. Electron decoupling uses frequency-modulated microwaves to mitigate the electron-nuclear dipolar interaction, improving signal intensity and resolution in DNP NMR experiments. Electron decoupling is combined with short DNP periods to encode electron spin information in polarized nuclear signal. The application of electron decoupling is expanded to a system of dilute 14N-endohedral C60.
Chair and Committee
Sophia E. Hayes
Richard Mabbs, Dewey Holten, Cornelius von Morze, Alexander B. Barnes,
Alaniva, Nicholas Howard, "Instrumentation for Dynamic Nuclear Polarization and Application of Electron Decoupling for Electron Relaxation Measurement" (2019). Arts & Sciences Electronic Theses and Dissertations. 1989.